DE3702967A1 - Mischungen von monoazofarbstoffen - Google Patents
Mischungen von monoazofarbstoffenInfo
- Publication number
- DE3702967A1 DE3702967A1 DE19873702967 DE3702967A DE3702967A1 DE 3702967 A1 DE3702967 A1 DE 3702967A1 DE 19873702967 DE19873702967 DE 19873702967 DE 3702967 A DE3702967 A DE 3702967A DE 3702967 A1 DE3702967 A1 DE 3702967A1
- Authority
- DE
- Germany
- Prior art keywords
- dye
- propyl
- dyes
- formula
- ethyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000975 dye Substances 0.000 title claims description 136
- 239000000203 mixture Substances 0.000 title claims description 54
- NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 title claims description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 20
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 17
- 239000002270 dispersing agent Substances 0.000 claims description 14
- 238000004043 dyeing Methods 0.000 claims description 11
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 125000000217 alkyl group Chemical group 0.000 claims description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims description 9
- 229910052736 halogen Inorganic materials 0.000 claims description 7
- 150000002367 halogens Chemical class 0.000 claims description 7
- 230000008878 coupling Effects 0.000 claims description 6
- 238000010168 coupling process Methods 0.000 claims description 6
- 238000005859 coupling reaction Methods 0.000 claims description 6
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
- 230000002209 hydrophobic effect Effects 0.000 claims description 4
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 3
- JEVCWSUVFOYBFI-UHFFFAOYSA-N cyanyl Chemical compound N#[C] JEVCWSUVFOYBFI-UHFFFAOYSA-N 0.000 claims description 3
- 239000002657 fibrous material Substances 0.000 claims description 3
- 229920003043 Cellulose fiber Polymers 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 239000000986 disperse dye Substances 0.000 claims description 2
- 239000000835 fiber Substances 0.000 claims description 2
- 239000003960 organic solvent Substances 0.000 claims description 2
- 239000004627 regenerated cellulose Substances 0.000 claims description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 24
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 18
- 239000007859 condensation product Substances 0.000 description 10
- 239000000843 powder Substances 0.000 description 7
- RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 description 6
- 229920000728 polyester Polymers 0.000 description 6
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 6
- 239000002202 Polyethylene glycol Substances 0.000 description 5
- -1 aromatic sulfonic acids Chemical class 0.000 description 5
- 239000006185 dispersion Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
- 238000000227 grinding Methods 0.000 description 5
- 229920001223 polyethylene glycol Polymers 0.000 description 5
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 5
- QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical compound C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 description 4
- 238000004040 coloring Methods 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 150000003254 radicals Chemical class 0.000 description 4
- 230000002829 reductive effect Effects 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- OCBFFGCSTGGPSQ-UHFFFAOYSA-N [CH2]CC Chemical compound [CH2]CC OCBFFGCSTGGPSQ-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 3
- 229910052794 bromium Inorganic materials 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 150000002989 phenols Chemical class 0.000 description 3
- 229920000151 polyglycol Polymers 0.000 description 3
- 239000010695 polyglycol Substances 0.000 description 3
- 235000010265 sodium sulphite Nutrition 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 238000007669 thermal treatment Methods 0.000 description 3
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical class C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 2
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 238000006193 diazotization reaction Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 2
- 239000003791 organic solvent mixture Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000001632 sodium acetate Substances 0.000 description 2
- 235000017281 sodium acetate Nutrition 0.000 description 2
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 description 2
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 229920002284 Cellulose triacetate Polymers 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 244000299507 Gossypium hirsutum Species 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 1
- VJMAITQRABEEKP-UHFFFAOYSA-N [6-(phenylmethoxymethyl)-1,4-dioxan-2-yl]methyl acetate Chemical compound O1C(COC(=O)C)COCC1COCC1=CC=CC=C1 VJMAITQRABEEKP-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 150000003857 carboxamides Chemical class 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000004108 freeze drying Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- HIEHAIZHJZLEPQ-UHFFFAOYSA-M sodium;naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 HIEHAIZHJZLEPQ-UHFFFAOYSA-M 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0046—Mixtures of two or more azo dyes
- C09B67/0051—Mixtures of two or more azo dyes mixture of two or more monoazo dyes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/92—Synthetic fiber dyeing
- Y10S8/921—Cellulose ester or ether
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/92—Synthetic fiber dyeing
- Y10S8/922—Polyester fiber
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/92—Synthetic fiber dyeing
- Y10S8/924—Polyamide fiber
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ZA880681A ZA88681B (en) | 1987-02-02 | 1987-02-01 | Mixtures of monoazo dyestuffs |
| DE19873702967 DE3702967A1 (de) | 1987-02-02 | 1987-02-02 | Mischungen von monoazofarbstoffen |
| EP88100576A EP0277529B1 (de) | 1987-02-02 | 1988-01-16 | Mischungen von Monoazofarbstoffen |
| DE8888100576T DE3879979D1 (de) | 1987-02-02 | 1988-01-16 | Mischungen von monoazofarbstoffen. |
| IN51/MAS/88A IN170554B (en]) | 1987-02-02 | 1988-01-25 | |
| US07/149,010 US4872883A (en) | 1987-02-02 | 1988-01-27 | Mixtures of monoazo dyestuffs |
| BR8800391A BR8800391A (pt) | 1987-02-02 | 1988-02-01 | Misturas de corantes monoazo,processo para sua preparacao e processo para tingir e estampar materiais |
| JP63019714A JPS63193962A (ja) | 1987-02-02 | 1988-02-01 | モノアゾ染料の混合物 |
| KR1019880000875A KR960005170B1 (ko) | 1987-02-02 | 1988-02-01 | 모노아조 염료 혼합물 및 이의 제조방법 |
| MX010288A MX167747B (es) | 1987-02-02 | 1988-02-02 | Mezclas de colorantes monoazoicos |
| JP2024573A JPH02242862A (ja) | 1987-02-02 | 1990-02-05 | モノアゾ染料の混合物 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19873702967 DE3702967A1 (de) | 1987-02-02 | 1987-02-02 | Mischungen von monoazofarbstoffen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE3702967A1 true DE3702967A1 (de) | 1988-08-11 |
Family
ID=6319998
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19873702967 Withdrawn DE3702967A1 (de) | 1987-02-02 | 1987-02-02 | Mischungen von monoazofarbstoffen |
| DE8888100576T Expired - Fee Related DE3879979D1 (de) | 1987-02-02 | 1988-01-16 | Mischungen von monoazofarbstoffen. |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE8888100576T Expired - Fee Related DE3879979D1 (de) | 1987-02-02 | 1988-01-16 | Mischungen von monoazofarbstoffen. |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US4872883A (en]) |
| EP (1) | EP0277529B1 (en]) |
| JP (2) | JPS63193962A (en]) |
| KR (1) | KR960005170B1 (en]) |
| BR (1) | BR8800391A (en]) |
| DE (2) | DE3702967A1 (en]) |
| IN (1) | IN170554B (en]) |
| MX (1) | MX167747B (en]) |
| ZA (1) | ZA88681B (en]) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0555678A1 (de) * | 1992-02-14 | 1993-08-18 | Hoechst Mitsubishi Kasei Co., Ltd. | Mischungen von Monoazofarbstoffen |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4026747A1 (de) * | 1990-08-24 | 1992-02-27 | Cassella Ag | Mischungen von monoazofarbstoffen |
| DE4437551A1 (de) * | 1994-10-20 | 1996-04-25 | Bayer Ag | Mischungen blauer Dispersionsazofarbstoffe |
| CN101812248B (zh) * | 2010-04-21 | 2013-07-24 | 浙江闰土股份有限公司 | 一种蓝色分散染料组合物 |
| FR3018043B1 (fr) * | 2014-03-03 | 2016-02-26 | Sigvaris | Manchon de compression sans coutures |
| WO2017083125A1 (en) | 2015-11-13 | 2017-05-18 | Intuitive Surgical Operations, Inc. | Stapler with composite cardan and screw drive |
| CN106046855B (zh) * | 2016-06-16 | 2017-08-18 | 浙江山峪科技股份有限公司 | 一种分散蓝染料组合物 |
| CN107312358B (zh) * | 2017-07-17 | 2019-07-26 | 浙江名毅新能源股份有限公司 | 一种分散染料组合物、其制备方法和应用 |
| US10863988B2 (en) | 2017-11-29 | 2020-12-15 | Intuitive Surgical Operations, Inc. | Surgical instrument with lockout mechanism |
| EP3752074B1 (en) | 2018-02-12 | 2024-11-27 | Intuitive Surgical Operations, Inc. | Surgical instrument with lockout mechanism |
| EP3758619B1 (en) | 2018-02-26 | 2024-04-03 | Intuitive Surgical Operations, Inc. | Surgical instrument with lockout mechanism |
| US12029473B2 (en) | 2018-05-31 | 2024-07-09 | Intuitive Surgical Operations, Inc. | Surgical instruments having a jaw locking mechanism |
| CN118750062A (zh) | 2018-10-19 | 2024-10-11 | 直观外科手术操作公司 | 内窥镜钱包线缝合外科设备 |
| EP3897405A4 (en) | 2018-12-21 | 2022-09-14 | Intuitive Surgical Operations, Inc. | ACTUATING MECHANISMS FOR SURGICAL INSTRUMENTS |
| CN113194846A (zh) | 2018-12-21 | 2021-07-30 | 直观外科手术操作公司 | 具有加强钉仓的外科手术器械 |
| WO2020131685A1 (en) | 2018-12-21 | 2020-06-25 | Intuitive Surgical Operations, Inc. | Surgical instruments with switches for deactivating and/or identifying stapler cartridges |
| US11857188B2 (en) | 2018-12-21 | 2024-01-02 | Intuitive Surgical Operations, Inc. | Articulation assemblies for surgical instruments |
| US11944302B2 (en) | 2019-04-15 | 2024-04-02 | Intuitive Surgical Operations, Inc. | Staple cartridge for a surgical instrument |
| US12011168B2 (en) | 2019-04-17 | 2024-06-18 | Intuitive Surgical Operations, Inc. | Surgical stapling instrument |
| EP4578419A2 (en) | 2019-05-31 | 2025-07-02 | Intuitive Surgical Operations, Inc. | Staple cartridge for a surgical instrument |
| US11786325B2 (en) | 2019-07-02 | 2023-10-17 | Intuitive Surgical Operations, Inc. | Remotely controlling a system using video |
| US12156654B2 (en) | 2019-10-18 | 2024-12-03 | Intuitive Surgical Operations, Inc. | Surgical instrument with adjustable jaws |
| US12324589B2 (en) | 2020-01-07 | 2025-06-10 | Intuitive Surgical Operations, Inc. | Surgical instruments for applying multiple clips |
| US11642129B2 (en) | 2020-01-15 | 2023-05-09 | Intuitive Surgical Operations, Inc. | Staple cartridge and drive member for surgical instrument |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4237048A (en) * | 1962-03-09 | 1980-12-02 | Bayer Aktiengesellschaft | Monoazo dyestuff containing di-cyano substituents ortho to the azo group |
| US4105655A (en) * | 1966-02-17 | 1978-08-08 | Bayer Aktiengesellschaft | Phenyl-azo-anilino dyestuff |
| CA994333A (en) * | 1972-04-07 | 1976-08-03 | Kunihiko Imada | Azo disperse dye mixtures |
| AT325179B (de) * | 1972-07-13 | 1975-10-10 | Bayer Ag | Farbstoffpraparate |
| DE3009635A1 (de) * | 1980-03-13 | 1981-09-24 | Cassella Ag, 6000 Frankfurt | Wasserunloesliche azofarbstoffe, ihre herstllung un verwendung |
| JPS57168953A (en) * | 1981-04-10 | 1982-10-18 | Sumitomo Chem Co Ltd | Production of mixed dye composition |
| DE3133926A1 (de) * | 1981-08-27 | 1983-03-17 | Cassella Ag, 6000 Frankfurt | Verfahren zum faerben von organischen loesungsmitteln, mineraloelprodukten, wachsen, kunststoffen und oberflaechenbelaegen |
| GB2108141B (en) * | 1981-09-04 | 1984-12-05 | Yorkshire Chemicals Ltd | Mixtures of disperse azo dyes |
| DE3216788A1 (de) * | 1982-05-05 | 1983-11-10 | Bayer Ag, 5090 Leverkusen | Farbstoffmischungen |
| DE3234186A1 (de) * | 1982-09-15 | 1984-03-15 | Cassella Ag, 6000 Frankfurt | Mischungen von monoazofarbstoffen |
| DE3347572C2 (de) * | 1983-12-30 | 1987-03-19 | Hoechst Ag, 6230 Frankfurt | Färben von Synthesefasern mit Farbstoffpräparationen von Mischungen oder Mischkristallen blauer Dispersions-Azofarbstoffe |
| DE3530339A1 (de) * | 1985-08-24 | 1987-02-26 | Hoechst Ag | Verfahren zum faerben von polyesterfasern feinen titers |
-
1987
- 1987-02-01 ZA ZA880681A patent/ZA88681B/xx unknown
- 1987-02-02 DE DE19873702967 patent/DE3702967A1/de not_active Withdrawn
-
1988
- 1988-01-16 EP EP88100576A patent/EP0277529B1/de not_active Expired - Lifetime
- 1988-01-16 DE DE8888100576T patent/DE3879979D1/de not_active Expired - Fee Related
- 1988-01-25 IN IN51/MAS/88A patent/IN170554B/en unknown
- 1988-01-27 US US07/149,010 patent/US4872883A/en not_active Expired - Lifetime
- 1988-02-01 KR KR1019880000875A patent/KR960005170B1/ko not_active Expired - Fee Related
- 1988-02-01 JP JP63019714A patent/JPS63193962A/ja active Granted
- 1988-02-01 BR BR8800391A patent/BR8800391A/pt not_active IP Right Cessation
- 1988-02-02 MX MX010288A patent/MX167747B/es unknown
-
1990
- 1990-02-05 JP JP2024573A patent/JPH02242862A/ja active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0555678A1 (de) * | 1992-02-14 | 1993-08-18 | Hoechst Mitsubishi Kasei Co., Ltd. | Mischungen von Monoazofarbstoffen |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0277529A3 (en) | 1989-05-10 |
| KR880010074A (ko) | 1988-10-06 |
| EP0277529A2 (de) | 1988-08-10 |
| BR8800391A (pt) | 1988-09-20 |
| DE3879979D1 (de) | 1993-05-13 |
| JPH0579264B2 (en]) | 1993-11-01 |
| MX167747B (es) | 1993-04-12 |
| JPS63193962A (ja) | 1988-08-11 |
| US4872883A (en) | 1989-10-10 |
| JPH02242862A (ja) | 1990-09-27 |
| KR960005170B1 (ko) | 1996-04-22 |
| JPH0579265B2 (en]) | 1993-11-01 |
| EP0277529B1 (de) | 1993-04-07 |
| IN170554B (en]) | 1992-04-11 |
| ZA88681B (en) | 1988-08-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8141 | Disposal/no request for examination |